Oxidative cleavage of allyl ethers by an oxoammonium salt.
نویسندگان
چکیده
A method to oxidatively cleave allyl ethers to their corresponding aldehydes mediated by an oxoammonium salt is described. Using a biphasic solvent system and mild heating, cleavage proceeds readily, furnishing a variety of α,β-unsaturated aldehydes and ketones.
منابع مشابه
A combined computational and experimental investigation of the oxidative ring-opening of cyclic ethers by oxoammonium cations.
The propensity of oxoammonium cations to facilitate the oxidative ring-opening of cyclic ethers to their corresponding distal hydroxy ketones is investigated. The reaction has been evaluated using experimental and computational methods to gain deeper insight into trends in reactivity.
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ورودعنوان ژورنال:
- Organic & biomolecular chemistry
دوره 13 14 شماره
صفحات -
تاریخ انتشار 2015